Catalytic Asymmetric Claisen Rearrangement in Natural Product Synthesis: Synthetic Studies toward (−)-Xeniolide F
- 17 November 2005
- journal article
- research article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 7 (25) , 5705-5708
- https://doi.org/10.1021/ol052462t
Abstract
The catalytic asymmetric Claisen rearrangement (CAC) of a highly substituted and functionalized α-alkoxycarbonyl-substituted allyl vinyl ether has been exploited to gain access to an advanced building block for the projected total synthesis of (−)-xeniolide F, the enantiomer of a xenicane diterpene isolated from a coral of the genus Xenia.Keywords
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