The Mechanism of Reaction between Poly(vinyl Alcohol) and Phosphorous Acid
- 1 March 1971
- journal article
- research article
- Published by Taylor & Francis in Journal of Macromolecular Science: Part A - Chemistry
- Vol. 5 (2) , 421-432
- https://doi.org/10.1080/00222337108069388
Abstract
The reaction mechanism of phosphorous acid and poly(vinyl alcohol) is presented. It has been found that there during this reaction mono- and diesters are formed in which most of the acid radicals are in the phosphonic form. To confirm the presence of this form in the product obtained, reactions with diethyleneamine and chloral have been carried out as characteristic tests for phosphonic groups. The occurrence of C—P bonds resistant to hydrolysis has been also found in the reaction product.Keywords
This publication has 3 references indexed in Scilit:
- Notes- Phosphonic Acid and Esters. II. Formation of Telomers in Olefin/Phosphorous Acid ReactionsThe Journal of Organic Chemistry, 1960
- Compounds containing carbon–phosphorus bondsQuarterly Reviews, Chemical Society, 1958
- LII.—The hydrolytic decomposition of phosphorus trichlorideJournal of the Chemical Society, Transactions, 1925