An algebraic approach to bound states of simple one‐electron systems
- 1 November 1977
- journal article
- research article
- Published by Wiley in International Journal of Quantum Chemistry
- Vol. 12 (5) , 875-896
- https://doi.org/10.1002/qua.560120510
Abstract
A very general realization of the so(2, 1) algebra, which easily follows from the basic commutation relations that are satisfied by any pair of mutually conjugate generalized coordinates and momenta, is constructed. Using special cases of this general realization, and closely following the well known derivation of the eigenvalue spectra of the angular‐momentum operators, based on the so(3) algebra, we derive the energy spectrum for the N‐dimensional isotropic harmonic oscillator, and for both the nonrelativistic and the relativistic N‐dimensional hydrogen atom. Special attention is given to a simple derivation of the form of these Hamiltonians in terms of the so(2, 1) algebra generators. In particular, the usually exploited tilting transformation is avoided, and the whole derivation is presented in an extremely simple and straightforward way. The present approach stresses the similarity and mutual relationship between the systems studied and, in addition to introducing some novel techniques and providing considerable insight into the overall structure of these problems, also has a definite pedagogical value.Keywords
This publication has 24 references indexed in Scilit:
- Axiomatic basis for spaces with noninteger dimensionJournal of Mathematical Physics, 1977
- Algebraic treatment of quantum-mechanical models with modified Coulomb potentialsAnnals of Physics, 1973
- Spectral properties of many-body Schrödinger operators with dilatation-analytic interactionsCommunications in Mathematical Physics, 1971
- A class of analytic perturbations for one-body Schrödinger HamiltoniansCommunications in Mathematical Physics, 1971
- O(2, 1) Algebra and the hydrogen atomTheoretical and Mathematical Physics, 1970
- The reformulations of the klein-gordon and dirac equations for the hydrogen atom to algebraic formsCzechoslovak Journal of Physics, 1969
- Remarks on the Relativistic Kepler Problem. II. Approximate Dirac-Coulomb Hamiltonian Possessing Two Vector InvariantsPhysical Review B, 1964
- Bemerkung zum VirialsatzThe European Physical Journal A, 1930
- ber den Grundterm der Zweielektronenprobleme von H?, He, Li+, Be++ usw.The European Physical Journal A, 1930
- Neue Berechnung der Energie des Heliums im Grundzustande, sowie des tiefsten Terms von Ortho-HeliumThe European Physical Journal A, 1929