Reaction of plasma-generated trifluoromethyl radicals with carbon tetraiodide and with bromobenzene; a new synthesis for trifluoromethyl organic compounds
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 128-129
- https://doi.org/10.1039/c39790000128
Abstract
The reaction of plasma-generated trifluoromethyl radicals with carbon tetraiodide leads to a mixture of perfluoroneopentane and perfluoro-t-butyl iodide in 97% total yield; bromobenzene reacts with trifluoromethyl radicals to give a 10–15% yield of trifluoromethylbenzene.Keywords
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