A new class of diosmium(IV) complexes containing both oxide and carboxylate bridges
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 1120b-1121
- https://doi.org/10.1039/c3981001120b
Abstract
The reactions of the OsVI complexes OsO2X2(PR3)2(X = Cl or Br) with refluxing carboxylic acids produce a new class of osmium dimers of the type Os2(µ-O)(µ-O2CR)2X4(PR3)2 whose structural details have been confirmed by an X-ray diffraction study of Os2(µ-O2CCH3)2Cl4(PPh3)2.Keywords
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