Primary yields in the ?-radiolysis of ammonia
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Transactions of the Faraday Society
- Vol. 66, 2199-2209
- https://doi.org/10.1039/tf9706602199
Abstract
The effects of varying pressure (100–700 mmHg), temperature (20–370°C) and dose (up to 7 × 1019 eV/g) on G(H2) and G(N2) in γ-irradiated ammonia gas have been studied. From the effects of additives, propene, benzene, carbon tetrachloride, methanol, isopropanol, cyclohexane, propane, nitric oxide, hydrazine on these yields, and assuming plausible reaction mechanisms, values of primary yields have been calculated. GH2 = 0.70±0.02, Ge= 3.4±0.6, GH= 7.0±0.6, GNH2 +2GNH= 11.9±0.1.Keywords
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