Determination of the molecular weight spread of narrow peaks in the gel‐permeation chromatograms of nitric acid‐degraded polyethylene

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Abstract
A method for the determination of the molecular weight spread in the narrow peaks in the GPC chromatograms of nitric acid‐degraded polyethylene is presented. It is found that polar endgroups added to the polymer chains during scission cause the peaks to be broader than those of paraffins with the same molecular weight spread. After allowing for this extra instrumental broadening, estimates are made of the molecular weight spread for unannealed and annealed single crystals of polyethylene and bulk polyethylene as a function of degradation time. It is proposed that after long degradation times the molecular weight spread is a measure of fluctuations in the original crystalline lamellar thickness.

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