E.s.r. identification of alkoxythiocarbonyl radicals as possible intermediates in barton deoxygenation of alcohols
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 683-684
- https://doi.org/10.1039/c39840000683
Abstract
O-Alkyl S-methyl dithiocarbonates react with trimethyltin radicals to afford alkoxythiocarbonyl radicals which undergo slow β-fission to alkyl radicals and carbon Oxysulphide.Keywords
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