Novel intermolecular carbon radical addition to a nitrone: asymmetric synthesis of α-amino acidsElectronic supplementary information (ESI) available: experimental procedures. See http://www.rsc.org/suppdata/cc/b2/b211570k/
- 14 January 2003
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 3,p. 426-427
- https://doi.org/10.1039/b211570k
Abstract
A nitrone was used as a synthetically useful radical acceptor in carbon–carbon bond-forming radical reactions; the intermolecular addition of alkyl radicals to chiral glyoxylic nitrone was studied; a high degree of stereocontrol in radical addition to glyoxylic nitrone was achieved to provide a new method for asymmetric synthesis of α-amino acids.Keywords
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