Syntheses of sugars with a chirally deuterated hydroxymethyl group. Part II. The synthesis of D-(6R)- and (6S)-(6-2H1)-galactose.
Open Access
- 1 January 1984
- journal article
- Published by Oxford University Press (OUP) in Agricultural and Biological Chemistry
- Vol. 48 (4) , 1049-1053
- https://doi.org/10.1271/bbb1961.48.1049
Abstract
D-(6R)- and (6S)-(6-2H1)-Galactose were regio- and stereospecifically synthesized through photobromination of 1, 6-anhydrogalactose derivatives. The (6S)-compound was prepared in a similar manner to our previous synthesis of D-(6S)-(6-2H1)-glucose. The inversion to the (6R)-galacto derivatives was performed via (6S)-(6-2H1)-6-ρ-toluenesulfonyl-l, 2;3, 4-di-O-isopropyridene-α-D-galactose.Keywords
This publication has 0 references indexed in Scilit: