SOME DERIVATIVES OF 4- t -BUTYLCYCLOHEXYL AND 1-MENTHOL-PHOSPHOROCHLORIDATES

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Abstract
cis and trans-4-t-Butylcyclohexanol and 1-menthol have been converted to the phosphorodichloridates with phosphorus oxychloride. Similar reaction with thiophosphoryl chloride afforded the phosphorodichloridothioates. By using 2 mol equivs. of 4-t-butylcyclohexanol, analogous condensations gave the corresponding phosphochloridates and chloridothioates, but with 1-menthol the reaction was unsuccessful. The various chloridates were characterized by preparation of a wide range of derivatives, e.g. amidates, azides, hydrazides, and hydrazones. These compounds are of interest as potential pesticides and their spectral features are discussed.