Ruthenium-Catalyzed Yne-Ene Cross Metathesis Binding to Solid Support and Cleavage by Pd0-Catalysis

Abstract
The solid phase synthesis of 1,3-dienes by yne-ene cross-metathesis involving binding of terminal alkenes to polystyrene resins, which contain propargyl ester groups, and their cleavage by Pd0-catalysis under C,C- or C,N-bond formation or reduction is demonstrated.

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