Copolymer Microstructure by High-Resolution NMR Studies
- 1 August 1967
- journal article
- research article
- Published by Taylor & Francis in Journal of Macromolecular Science: Part A - Chemistry
- Vol. 1 (5) , 891-908
- https://doi.org/10.1080/10601326708053742
Abstract
The monomer and configurational sequences of several radical copolymers between substituted styrenes and acrylates have been examined by analyzing the high-resolution NMR spectra with the previously reported treatment of the styrene-methyl methacrylate system. The analyses have led to the conclusion that the monomer sequence distribution is just as expected from the usual copolymerization theory with r 1 and r 2.Keywords
This publication has 20 references indexed in Scilit:
- Microstructure in copolymers. I. Determination of isobutylene and vinylidene chloride diads by NMR spectroscopyJournal of Polymer Science Part B: Polymer Letters, 1966
- NMR study of styrene‐methyl acrylate copolymer obtained by radical polymerizationJournal of Polymer Science Part B: Polymer Letters, 1965
- Nmr study of styrene‐methyl methacrylate copolymer obtained by anionic polymerizationJournal of Polymer Science Part B: Polymer Letters, 1965
- NMR study of styrene‐methyl methacrylate copolymer obtained by radical polymerizationJournal of Polymer Science Part B: Polymer Letters, 1965
- Methoxy and α‐methyl proton resonance in styrene‐methyl methacrylate copolymersJournal of Polymer Science Part B: Polymer Letters, 1965
- Studies in Stereochemistry. XXXIII. Approaches to Models for 1,3-Asymmetric InductionJournal of the American Chemical Society, 1963
- Polymer NMR spectroscopy. VI. Methyl methacrylate–styrene and methyl methacrylate–α‐methylstyrene copolymersJournal of Polymer Science, 1962
- The Correlation of Solvent Effects on the Stereoselectivities of Diels-Alder Reactions by Means of Linear Free Energy Relationships. A New Empirical Measure of Solvent PolarityJournal of the American Chemical Society, 1962
- Structural and Compositional Analysis of Vinylidene Fluoride-Hexafluoropropylene Copolymers by Nuclear Magnetic Resonance SpectroscopyJournal of the American Chemical Society, 1960
- Studies in Stereochemistry. XXX. Models for Steric Control of Asymmetric Induction1Journal of the American Chemical Society, 1959