Dipole moments of substituted chloroformates in dilute benzene solutions
- 15 December 1967
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 45 (24) , 3177-3179
- https://doi.org/10.1139/v67-511
Abstract
The dipole moments of methyl, ethyl, n-propyl, n-butyl, amyl, and phenyl chloroformate as well as n-butyl formate in dilute benzene solution at 25 °C were determined. The experimental results suggest that the configuration of the chloro-esters differs from the configuration of the unchloroinated esters, viz. the ester hydrocarbon group and the chlorine atom are cis to each other.Keywords
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