TlI[C(SiMe3)3]—An Alkylthallium(I) Compound with a Distorted Tetrahedron of Tl Atoms in the Solid State
- 3 February 1997
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 36 (1-2) , 64-65
- https://doi.org/10.1002/anie.199700641
Abstract
Weak thallium–thallium interactions are present in the thallium tetrahedron of the crystalline alkylthallium(I) compound Tl[C(SiMe3)3], which is easily accessible from cyclopentadienylthallium(I) and tris(trimethylsilyl)methyllithium. In solution, however, only the monomer of the extremely thermally sensitive compound can be detected.Keywords
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