Determination of Phosphorus and Silicon with an Inductively Coupled Plasma Detector for Reversed-Phase Chromatography

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Abstract
A single-channel inductively coupled plasma (ICP) is evaluated as an element-specific detector for reversed-phase high-pressure liquid chromatography (HPLC). Application of the system to the separation of several phosphorus compounds using methanol:water and acetonitrile: water mobile phases is discussed. Results using this instrument for the separation of organic interferences from siloxane compounds followed by quantitative silicon analyses by ICP are presented.

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