Efficient Catalysis of Ammonia Borane Dehydrogenation
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- 24 August 2006
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 128 (37) , 12048-12049
- https://doi.org/10.1021/ja062419g
Abstract
In the presence of an iridium pincer complex, dehydrogenation of ammonia borane (H3NBH3) occurs rapidly at room temperature in tetrahydrofuran to generate 1.0 equivalent of H2 and [NH2BH2]5. A metal borohydride complex has been isolated as a dormant form of the catalyst which can be reactivated by reaction with H2.Keywords
This publication has 18 references indexed in Scilit:
- Thermodynamic Properties of Molecular Borane Amines and the [BH4-][NH4+] Salt for Chemical Hydrogen Storage Systems from ab Initio Electronic Structure TheoryThe Journal of Physical Chemistry A, 2005
- Coordination Modes of Boranes in Polyhydride Ruthenium Complexes: σ-Borane versus DihydridoborateOrganometallics, 2005
- Heterogeneous or Homogeneous Catalysis? Mechanistic Studies of the Rhodium-Catalyzed Dehydrocoupling of Amine-Borane and Phosphine-Borane AdductsJournal of the American Chemical Society, 2004
- Synthesis and Properties of Iridium Bis(phosphinite) Pincer Complexes (p-XPCP)IrH2, (p-XPCP)Ir(CO), (p-XPCP)Ir(H)(aryl), and {(p-XPCP)Ir}2{μ-N2} and Their Relevance in Alkane Transfer DehydrogenationOrganometallics, 2004
- Iridium Bis(phosphinite) p-XPCP Pincer Complexes: Highly Active Catalysts for the Transfer Dehydrogenation of AlkanesJournal of the American Chemical Society, 2004
- Iridium PCP pincer complexes: highly active and robust catalysts for novel homogeneous aliphatic dehydrogenationsChemical Communications, 1999
- Synthesis and structure of a [(1,2-phenylenedioxy)boryl]iridium hydride complex: a model system for studying catalytic hydroborationOrganometallics, 1990
- Boryliridium and boraethyliridium complexes fac-[IrH2(PMe3)3(BRR')] and fac-[IrH(PMe3)3(.eta.2-CH2BHRR')]Journal of the American Chemical Society, 1990
- (Pentamethylcyclopentadienyl)iridium polyhydride complexes: synthesis of intermediates in the mechanism of formation of (pentamethylcyclopentadienyl)iridium tetrahydride and the preparation of several iridium(V) compoundsJournal of the American Chemical Society, 1985
- Boron-Nitrogen Chemistry. I. Syntheses and Properties of New Cycloborazanes, (BH2NH2)n1,2Journal of the American Chemical Society, 1966