Reactions of propynylplatinum(II) compounds

Abstract
The alkynylplatinum(II) compounds trans-Pt-(CCR)2L2 and trans-PtCl(CCR)L2(RMe or CF3; LPMe2Ph) show interesting chemistry based on reaction at either the organic or inorganic site of unsaturation; a new synthesis of alkoxy-carbene ligands and evidence for platinum-stabilized carbonium ion intermediates are reported.

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