The preparation of 2-ethoxy-4,5-diphenyl-1,3-dioxole and its conversion into diphenylethyne and diphenylketen

Abstract
The acid-catalysed reaction of benzoin with ethyl orthoformate yields 2-ethoxy-4,5-diphenyl-1,3-dioxole which on pyrolysis in the presence of a carboxylic acid forms diphenylethyne: pyrolysis under reduced pressure of the compound alone forms diphenylethyne and diphenylketen.

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