Synthesis, photophysics and thermal redox reactions of a [{Au(dppn)Cl}2]2+dimer with an unsupported AuII–AuIIbond
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 10,p. 1173-1174
- https://doi.org/10.1039/cc9960001173
Abstract
A novel binuclear gold(II) complex containing a formal AuII–AuII bond is synthesized and characterized by X-ray crystallography; the compound is shown to possess rich photophysical and thermal redox properties.Keywords
This publication has 20 references indexed in Scilit:
- Synthesis and Structure of[Au4(C6F5)2{(PPh2)2CH}2(PPh3)2](ClO4)2.cntdot.4CH2Cl2, a Complex with Two Direct Gold-Gold BondsOrganometallics, 1994
- Mixed-valent linear chains of gold atoms. X-ray structure of [{(2,4,6-C6F3H2)Au(CH2PPh2CH2)2Au}2Au(CH2PPh2CH2)2Au](ClO4)2Organometallics, 1994
- A Mixed‐Valent Pentanuclear Gold Complex Containing a Linear Au ChainAngewandte Chemie International Edition in English, 1991
- Synthesis of dinuclear gold-(I), -(II), and -(III) complexes containing ylide ligands [(RO2C)CHPPh2CH(CO2R)]–(R = Me or Et) and trinuclear gold(I) complexes containing ylide ligands [(RO2C)CPPh2CH(CO2R)]2–(R = Me or Et)J. Chem. Soc., Dalton Trans., 1990
- Symmetric addition of sulfur dioxide to linear bi- and trinuclear gold(I) compounds. Partial oxidation to form [Au(.mu.-(CH2)2PPh2)]2(SO2)2 and Au2Pt(.mu.-C,S-CH2PPh2S)4(SO2)2Journal of the American Chemical Society, 1989
- Synthesis and characterization of the luminescent dithiolate-bridged dimer [n-Bu4N]2[Au(i-MNT)]2 (i-MNT = S2C2(CN)22-) and its structurally characterized, metal-metal-bonded gold(II) oxidation product [Ph4As]2[Au(i-MNT)Cl]2Inorganic Chemistry, 1988
- Coupling of Cyclometalated Phenylphosphanes in Dinuclear Gold(II)‐ComplexesAngewandte Chemie International Edition in English, 1987
- Synthesis and x-ray crystal structures of [Au(CH2)2PPh2]2(CF3)2, [Au(CH2)2PPh2]2(C6F5)2, and [PPN][Au(C6F5)4]: two dinuclear gold(II) ylide complexes containing alkyl and aryl ligands and a tetrakis(pentafluorophenylaurate(III) anion complexInorganic Chemistry, 1987
- Mono- and bi-nuclear gold(I), gold(II), and gold(III) perhalogenoaryl complexes with the ligand bis(diphenylphosphino)amine. Crystal and molecular structure of µ-[bis(diphenylphosphino)amine]-dichlorobis(pentafluorophenyl)digold(II)J. Chem. Soc., Dalton Trans., 1986
- Experimental and theoretical studies of dinuclear gold(I) and gold(II) phosphorus ylide complexes. Oxidative addition, halide exchange, and structural properties including the crystal and molecular structures of [Au(CH2)2PPh2]2 and [Au(CH2)2PPh2]2(CH3)BrJournal of the American Chemical Society, 1985