THE HYDROGEN-ABSTRACTION REACTIONS IN THE PHOTOLYSIS OF PENTAFLUOROPROPANAL AND HEPTAFLUOROBUTANAL
- 1 September 1962
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 40 (9) , 1830-1835
- https://doi.org/10.1139/v62-278
Abstract
The main products of the photolysis of the aldehydes at 3130 Å were determined and the rates of H-atom abstraction relative to radical recombination were measured. They are [Formula: see text] for C2F5CHO, and [Formula: see text] for C3F7CHO. The derived Arrhenius parameters are compared with those determined in the photolysis of CF3CHO, and also with the non-fluorinated aldehydes.Keywords
This publication has 1 reference indexed in Scilit:
- The reactions of trifluoromethyl radicals with aromatic hydrocarbons. Part 1.—Benzene, toluene and o-xyleneTransactions of the Faraday Society, 1960