Dissociation of the Hydroxyl Radical in an rf Discharge
- 1 January 1962
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 36 (1) , 239-240
- https://doi.org/10.1063/1.1732303
Abstract
The following information was obtained on by‐product concentrations from the rf discharge of water vapor—molecular oxygen mixtures at H2O pressures from 50 to 200 μ and O2 pressures from 0 to 300 μ: the absence of the OH species below the region of 100 μ water vapor pressure, together with the absence of the O species above the region of 130‐μ water vapor pressure, the independence of the OH and O cutoff points on the amount of oxygen added to the water vapor previous to the discharge, OH enhancements of as high as a factor of 5 to 1 upon addition of sufficient oxygen to the mixture, and total OH concentration throughout the recorded pressure range of less than 1%.Keywords
This publication has 2 references indexed in Scilit:
- Microwave Zeeman Effect of Free Hydroxyl RadicalsPhysical Review B, 1961
- Microwave Spectra of the Free Radicals OH and ODPhysical Review B, 1955