Mechanism for initial carbene formation in olefin metathesis over fixed Mo catalysts
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 130-132
- https://doi.org/10.1039/c39830000130
Abstract
It is indicated that the initial carbene for ethene or propene metathesis over active fixed Mo catalysts with well defined reaction sites is formed by a 1,2-hydrogen shift via a molybdenum–n-alkenyl intermediate.Keywords
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