Some further studies on the synthesis of glycopeptide derivatives: 2-acetamido-2-deoxy-β-d-glucopyranosylamine derivatives
- 1 October 1966
- journal article
- research article
- Published by Portland Press Ltd. in Biochemical Journal
- Vol. 101 (1) , 184-190
- https://doi.org/10.1042/bj1010184
Abstract
The isolation, characterization and properties of 2 by-products in the preparation of 2-acetamido-3, 4, 6-tri-O-acetyl-2-deoxy-[beta]-D-glucopy- ranosylamine are described. They are bis-(2-acetamido-2-deoxy-D-glucopyranosyl)amines. An independent synthesis of the bis-glyco-pyranosylamines is reported and conditions are given for their preparation in high yield. Further improvements are given for the synthesis of 2-acetamido-l-N-([beta]-L-aspartyl)-2-deoxy-[beta]-D-glucopyrano-sylamine and the a -L-aspartyl isomer. The synthesis of 2-acetamido-l-N-acetyl-2-deoxy-[beta]-D-glucopyranosylamine is described.This publication has 8 references indexed in Scilit:
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