Longitudinal Spin Relaxation in Solid
- 6 January 1964
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 133 (1A) , A17-A25
- https://doi.org/10.1103/physrev.133.a17
Abstract
Calculations of the spin-lattice relaxation time, , for nuclei in solid are made and the results are compared with experiment. A simple heuristic argument is first used which treats the two important relaxation mechanisms—diffusion and Zeeman-exchange coupling—as effectively independent and then a more precise calculation is made which takes into account interference effects. An expression for the exchange integral is obtained as a function of molar volume which, compared with the experiment, indicates an effective, reduced dipolar coupling. The effect of zero point motion on the dipolar interaction is investigated and using a very simple lattice model, it is found to be an important (but not necessarily the major) factor.
Keywords
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