A Route to Vicinal Diamines from the Samarium(II) Iodide-Mediated Coupling of Aldimines
- 1 April 1990
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 20 (7) , 981-987
- https://doi.org/10.1080/00397919008052801
Abstract
A new method to construct vicinal diamines from aldimines mediated by the one electron reductant, samarium diiodide is described. The reaction probably involves a ketyl-like radical coupling mechanism.Keywords
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