Synthesis of isoquinolines by intramolecular aza-Wittig reaction
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 776-777
- https://doi.org/10.1039/c39840000776
Abstract
Isoquinolines (3) and (5) are formed under miled neutral conditions by intramolecular aza-Wittig reactions of iminophospranes, readily derived from azides (1) and (4) with trithyl phosphite, the azafluranthene (7) can also be prepared from the isolable iminophosphoranes (8), (9), and (10).Keywords
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