A new synthetic method for the preparation of 2,8-disubstituted oxocane derivatives: synthesis of lauthisan and laurenan
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 565-567
- https://doi.org/10.1039/c39860000565
Abstract
The cis-disubstituted oxocanes lauthisan (1) and laurenan (2) have been prepared from the lactone precursors (9b) and (9a) respectively by a sequence in which the key steps were methylenation and stereoselective hydroboration of the resulting enol ethers (11b) and (11a).Keywords
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