Linear Chain Ferromagnetic Charge Transfer Compounds
- 1 January 1986
- journal article
- research article
- Published by Wiley in Israel Journal of Chemistry
- Vol. 27 (4) , 363-373
- https://doi.org/10.1002/ijch.198600055
Abstract
Charge transfer complexes possessing a … DADA … structure with both the donor, D, and acceptor, A, being S = 1/2 radicals may exhibit cooperative magnetic phenomena. The complex [Fe(C5Me5)2]+·[TCNQ]−· exhibits metamagnetic behavior. The similarly structured [TCNE]−· and [C4(CN)6]−· complexes are ferromagnets, whereas the [DDQ]−· salt is a paramagnet. The high temperature magnetic susceptibility obeys the Curie‐Weiss expression with θ = + 30, + 30, and + 3 for the [TCNE]−·, [C4(CN)6]−·, and [TCNQ]−· salts, respectively. The ferromagnetic [TCNE]−· salt exhibits zero field Zeeman split 57Fe Mossbauer spectra with an internal field of 425.6 kOe at 4.23 K. After reviewing the current papers discussing ferromagnetism in molecular (organic) compounds, a qualitative model consistent with the necessary bulk spin alignment required for a ferromagnet is presented.Keywords
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