Enthalpies of formation of adamantanoid compounds. Part 3.—Adamantanecarboxylic acids
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
- Vol. 69, 1257-1260
- https://doi.org/10.1039/f19736901257
Abstract
The standard enthalpies of combustion for adamantane-1- and -2-carboxylic acids have been measured. They are ΔH° c=–(1427.38 ± 0.86) and –(1431.18 ± 0.90) kcal mol–1 respectively. The corresponding standard enthalpies of formation ΔH° f(C11H16O2, c) are –(153.70) and –(149.90) kcal mol–1. The enthalpy of isomerization is compared with the values obtained in similar conformational changes in cyclic molecules.Keywords
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