The Effect of Thermal Treatment on the Properties of Hydroxy-Al and Hydroxy-Ga Pillared Montmorillonite and Beidellite
- 1 June 1994
- journal article
- Published by Mineralogical Society in Clay Minerals
- Vol. 29 (2) , 153-167
- https://doi.org/10.1180/claymin.1994.029.2.02
Abstract
The pillaring process of montmorillonite and beidellite with Al and Ga polymers has been studied using XRD, IR,27Al,71Ga, and29Si MAS NMR, TGA, TEM, N2adsorption and chemical analyses. The Al adsorption maximum for montmorillonite is close to 5.5 mEq Al/g clay, whereas the maximum for Ga is higher. Basal spacings of both Ga- and Al-pillared clays vary between 16.7 and 18.8 Å. Freeze-drying of pillared products followed by calcination yielded more regular pillared structures. Pillaring montmorillonite increased the BET surface area from 35 m2/g to 350 m2/g mainly by the creation of micropores 3+cations.Keywords
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