DIE MICHAELIS-ARBUZOV-REAKTION PERHALOGENIERTER OLEFINE III: TRIFLUORVINYLHALOGENIDE CF2[dbnd] CFX1
- 1 May 1981
- journal article
- research article
- Published by Taylor & Francis in Phosphorus and Sulfur and the Related Elements
- Vol. 10 (1) , 127-132
- https://doi.org/10.1080/03086648108078281
Abstract
Die Umsetzungen von CF2[dbnd]CFX mit (RO)3P werden untersucht, CFJ[dbnd]CFP(O)(OiC3H7)2 und (iC3H7O)2(O)PCF[dbnd]CFP(O)(OiC3H7)2 erhalten. 1H-, 19F-, 31P-NMR im Einzel- und Doppelresonanzverfahren bestimmen die vorzeichenkorrekten NMR-Parameter. Reactions of CF2[dbnd]CFX and (RO)3P are investigated. CFJ[dbnd]CFP(O)(OiC3H7)2 and (iC3H7O)2(O)CF[dbnd]CF(O)(OiC3H7)2 are obtained. 1H-, 19F-, 31P-NMR in single and double resonance mode yielded signs and magnitudes of NMR parameters.Keywords
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