Vibrational spectra of the chloro- and bromo-π-allylpalladium dimers and of the π-2-methylallyl analogues
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 1808-1813
- https://doi.org/10.1039/j19700001808
Abstract
Raman and i.r. spectra of the title compounds are reported and assigned for both solids and solutions. ν(C–H) modes show correlationsplitting, but the remainder of the internal modes of the π-allyl ligands can be discussed in terms of Cs local symmetry. ν(C–C–C) modes of the allyl skeleton are placed ca. 1383 and 1020 cm.–1 in the parent complex.Keywords
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