A Dicubane-Like Tetrameric Nickel(II) Azido Complex

Abstract
A combination of azido and dipyridylketone (dpk) ligands led to the isolation of the tetranuclear NiII complex 1 (dpkOH and dpkOCH3 result from solvolysis of dpk). The complex exhibits ferromagnetic behavior, and its structure can be described as a dicubane unit with two missing vertices (see picture).

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