Étude de la relaxation magnétique nucléaire dans le trichlorosilane liquide
- 1 January 1975
- journal article
- Published by EDP Sciences in Journal de Physique
- Vol. 36 (9) , 897-904
- https://doi.org/10.1051/jphys:01975003609089700
Abstract
L'étude de la relaxation du chlore 35 et la détermination de la vitesse de relaxation dipôle-dipôle intramoléculaire silicium 29-proton permettent de montrer l'anisotropie de réorientation dans le mouvement de la molécule de trichlorosilane en phase liquide. Le principal mécanisme de relaxation du silicium 29 dans ce produit provient de l'interaction spin-rotation, ce qui permet, de plus, de mettre en évidence les effets inertiels dans la diffusion lorsque la température s'élèveKeywords
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