Asymmetric α-amino acid synthesis: synthesis of (+)-polyoxamic acid using a [3,3]allylic trifluoroacetimidate rearrangement
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 717-719
- https://doi.org/10.1039/c39890000717
Abstract
The stereoselective [3,3] rearrangement of allylic trifluoroacetimidate (15) has been used in a synthesis of (+)-polyoxamic acid (1).Keywords
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