Syntheses and properties of aminomethyl complexes of manganese and rhenium
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 11,p. 1096-1099
- https://doi.org/10.1039/dt9750001096
Abstract
The interaction of a range of aminomethyltrimethyltins with carbonyl halides of manganese and rhenium has afforded the yellow volatile compounds [(η2-R2NCH2)M(CO)4](M = Mn and Re). In these complexes the aminomethyl ligand functions as a formally three-electron donor, and the ligand is removed by halogen to form the corresponding methyleneammonium halide.Keywords
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