Synthesis of Methyl Formate by Electrocatalytic Oxidation of Methanol in the Gas Phase Using Heteropoly and Phosphoric Acids

Abstract
A simple method for electrocatalytic conversion of methanol to methyl formate in the gas phase has been demonstrated. The method using heteropoly acids and phosphoric acid in a flow of methanol vapor could be applied successfully for synthesizing methyl formate with high one-pass yield and selectivity.