Reaction of 1,1-dicyclopropylethylene with pentacarbonyliron: a novel carbon monoxide insertion coupled with a double cyclopropane ring-opening
- 1 January 1969
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 15,p. 883-884
- https://doi.org/10.1039/c29690000883
Abstract
1,1-Dicyclopropylethylene reacts with pentacarbonyliron to give 2-cyclopropylpenta-1,3-dienetricarbonyliron (V) and, after a longer reaction time, a mixture of (V) and 3-(1′-propenyl)-cyclohex-2-enonetricarbonyliron—a carbon monoxide insertion reaction.Keywords
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