The appeearance of polar forms of 1,4-Dioxan at temperatures above 200°C
- 1 January 1958
- journal article
- research article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 11 (2) , 147-153
- https://doi.org/10.1071/ch9580147
Abstract
The total polarization of 1,4-dioxan vapour is reported for 20 temperatures between 118 and 365 �C. The results, considered together with 19 others previously recorded over a range down to 56 �C, indicate the generation of polar forms at higher temperatures, and confirm an earlier suggestion by Gibbs (1961). The variation of P with 1/T �K is shown graphically and may also be qualitatively forecast by equations having a semi-empirical character ; a steep rise of P is predicted as T is increased above about 200 �C.Keywords
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