Chemical Fixation of Carbon Dioxide Catalyzed by Binaphthyldiamino Zn, Cu, and Co Salen-Type Complexes
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- 8 January 2003
- journal article
- research article
- Published by American Chemical Society (ACS) in The Journal of Organic Chemistry
- Vol. 68 (4) , 1559-1562
- https://doi.org/10.1021/jo020191j
Abstract
Binaphthyldiamino salen-type Zn, Cu, and Co complexes can efficiently catalyze reactions of epoxides with carbon dioxide in the presence of various catalytic amounts of organic bases. The simplest binaphthyldiamino salen-type Zn complex gave the five-membered cyclic carbonate 2 in excellent yield in the presence of triethylamine. A Lewis acid and Lewis base cocatalyzed mechanism is proposed.Keywords
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