Synthesis of optically active ‘Dewar’ benzenes; asymmetric induction
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 972
- https://doi.org/10.1039/c39750000972
Abstract
The optically active ‘Dewar’ benzene (4) has been prepared from the menthyl, bornyl, or s-octyl acetylenic esters (1) and the cyclobutane (2) followed by hydrolysis; the product with the highest optical purity was obtained from the menthyl ester.Keywords
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