The conformation of eight-membered 3,2′-O-isopropylidene acetals of some common disaccharides
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 11,p. 1867-1873
- https://doi.org/10.1039/p29890001867
Abstract
The conformation of the eight-membered 3,2′-O-isopropylidene acetals from methyl β-cellobioside, benzyl β-lactoside, and methyl β-maltoside has been investigated using 1H and 13C n.m.r. spectroscopy and molecular-mechanics calculations. The interglycosidic eight-membered rings strongly restrict the conformational mobility around the glycosidic bond.This publication has 13 references indexed in Scilit:
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