Lower bounds to the Weizsäcker correction

Abstract
Two rigorous lower bounds to T2, the Weizsäcker correction, have been derived: T2(π4322324)×(ρ3(r)dr)13=T2B1[ρ] and T2>(172)<r2>=T2B2[ρ]. The first bound is universal, while the second holds only for spherically symmetric bound systems. Numerical comparisons employing the Hartree-Fock atomic densities reveal that the bounds are not very tight; however, the ratios T2T2B1 and T2T2B2, though decreasing slowly with increasing Z, remain fairly constant for Z=2 through 24. The implications of these bounds in the variational context are discussed.

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