Conducting polymer solutions: An EPR and INDO/CI study of a radical cation observed in conducting poly( p-phenylene sulfide) solutions
- 1 October 1985
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 83 (7) , 3681-3684
- https://doi.org/10.1063/1.449844
Abstract
We report here the observation of resolved EPR hyperfine couplings for the conducting polymer AsF5‐doped poly( p‐phenylene sulfide), dissolved in liquid AsF3. Correlation of the EPR and INDO results indicates that the observed signal is due to a nonplanar sulfur‐centered radical cation with the hyperfine pattern arising from the coupling of the electron to the four meta 1H’s on the adjacent phenyl rings.Keywords
This publication has 14 references indexed in Scilit:
- Conducting Organic MaterialsScience, 1984
- Organic metalsNature, 1984
- Electrochromism for organic materials in polymeric all-solid-state systemsApplied Physics Letters, 1983
- An EPR study of the reaction between poly(p-phenylene sulfide) and electron-acceptor dopantsThe Journal of Chemical Physics, 1983
- Carbon-13 magic angle NMR study of the isomerization of cis- to trans-polyacetyleneJournal of the American Chemical Society, 1981
- Synthese, Charakterisierung und Kristallstruktur von Bis{4‐(2‐thienyl)selenolo[3,4‐ b ]thiophen‐6‐yl}diselenidEuropean Journal of Inorganic Chemistry, 1981
- INDO characterization of α-halogen interaction in planar radicals from irradiated 5-halouracilsJournal of Magnetic Resonance (1969), 1980
- ESR and ENDOR Studies of Ion Formation in X-Irradiated Thiodiglycollic AcidThe Journal of Chemical Physics, 1968
- Electron Spin Resonance Absorption in Metals. I. ExperimentalPhysical Review B, 1955
- Electron Spin Resonance Absorption in Metals. II. Theory of Electron Diffusion and the Skin EffectPhysical Review B, 1955