C–O BOND CLEAVAGE IN ALLYL PHENYL ETHER INDUCED BY THE PHOTOREACTION OF A HYDRIDOCOBALT COMPLEX

5 May 1985

journal article
Published by Oxford University Press (OUP) in Chemistry Letters

Vol. 14 (5) , 621-622
https://doi.org/10.1246/cl.1985.621

Abstract

C–O bond cleavage in allyl phenyl ether giving propylene has been found to proceed via an identical intermediate with that for catalytic double-bond migration giving propenyl phenyl ether by means of laser flash photolysis and product analysis for continuous irradiation.

Keywords

PHENYL ETHER
HYDRIDOCOBALT COMPLEX
ETHER INDUCED
ALLYL PHENYL
BOND CLEAVAGE
PHOTOREACTION

This publication has 1 reference indexed in Scilit:

Absolute rate constants for the coordination of olefins to a transient coordinatively unsaturated cobalt complex
Journal of Organometallic Chemistry, 1984