Synthesis of a polyurethane containing Mo-Mo bonds in the backbone
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 1459-1461
- https://doi.org/10.1039/c39890001459
Abstract
A polyurethane with Mo-Mo bonds in the backbone was synthesized by reaction of the ‘diol’{η5-C5H4C(O)CH2OH}2Mo2(CO)6 with 1,6-hexamethylene di-isocyanate; irradiation of the polymer in tetrahydrofuran solution results in cleavage of the metal–metal bonds and subsequent fragmentation of the polymer.Keywords
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