ACTIVATION OF POLYHALOALKANES BY PALLADIUM CATALYST. FACILE ADDITION OF POLYHALOALKANES TO OLEFINS
- 5 August 1981
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 10 (8) , 1169-1170
- https://doi.org/10.1246/cl.1981.1169
Abstract
Addition reaction of CCl4, CCl3Br, and CCl3CO2Me to olefins proceeded under mild conditions to afford 1 : 1 adduct in high yields by using palladium–phosphine complexes as a catalyst in the presence of bases. The reaction proceeded even at room temperature.This publication has 5 references indexed in Scilit:
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- Reactions of Atoms and Free Radicals in Solution. X. The Addition of Polyhalomethanes to OlefinsJournal of the American Chemical Society, 1947