Use of π-allyltricarbonyliron lactone complexes in the synthesis of taurospongin A: a potent inhibitor of DNA polymerase β and HIV reverse transcriptase
- 24 April 2003
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Organic & Biomolecular Chemistry
- Vol. 1 (10) , 1664-1675
- https://doi.org/10.1039/b301676p
Abstract
The total synthesis of taurospongin A by two new approaches has been achieved where π-allyltricarbonyliron lactone complexes have been used to control highly stereoselective additions of the nucleophiles to a carbonyl unit located in the side chain of these complexes.Keywords
This publication has 56 references indexed in Scilit:
- Synthese, Kristallstruktur und Reaktionen neuartiger metallacyclischer Dioxo‐ und Aminooxocarben‐Komplexe des EisensEuropean Journal of Inorganic Chemistry, 1994
- Tricarbonyliron lactone complexes in organic synthesisPublished by Walter de Gruyter GmbH ,1994
- Total synthesis of the ionophore antibiotic CP-61,405 (routiennocin)Tetrahedron, 1992
- The use of π-allyltricarbonyliron lactone complexes in the synthesis of the β-lactone esterase inhibitor (−)-valilactone.Tetrahedron, 1991
- Synthesis of the alkaloids (−)-heliotridane and (−)-isoretronecanol via π-allyltricarbonyliron lactam complexes.Tetrahedron Letters, 1991
- Natural product synthesis using π-allyltricarbonyliron lactone complexes: Synthesis of parasorbic acid, the carpenter bee pheromone and malyngolideJournal of Organometallic Chemistry, 1985
- Isolation, Characterisation and Oxidation of Isomeric Ferrelactone Complexes.Journal of Organometallic Chemistry, 1979
- Organische Synthesen mit Übergangsmetallkomplexen, 8. Untersuchungen zur Synthese ungesättigter δ‐Lactone durch Cyclocarbonylierung von Vinyloxiranen mit Übergangsmetall‐KomplexenEuropean Journal of Inorganic Chemistry, 1979
- Lactones and Lactams by Light‐Induced Reaction of 2‐Vinyloxiranes and 2‐Vinylaziridines with Pentacarbonyliron—Insertion of Carbon Monoxide into an Iron‐Nitrogen σ BondAngewandte Chemie International Edition in English, 1974
- Über π‐Allyl‐acyl‐Eisencarbonyl‐VerbindungenHelvetica Chimica Acta, 1964