Stereodirecting substituent effects during enzyme-catalysed synthesis of cis-dihydrodiol metabolites of 1,4-disubstituted benzene substrates
- 1 January 1993
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 974-976
- https://doi.org/10.1039/c39930000974
Abstract
The cis-dihydrodiol enantiomer preferentially formed, by dioxygenase-catalysed oxidation of 1,4-disubstituted benzene substrates in growing cultures of Pseudomonas putida UV4, is found to be largely controlled by the relative size of the substituents.Keywords
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